The chemistry of rhenium and manganese carbonyl complexes bearing heterocyclic thiolate ligands: Mono‒, di‒, tri‒, and tetranuclear complexes

نویسندگان

چکیده

This article provides an overview of the rich chemistry rhenium and manganese decacarbonyls, M2(CO)10 (M = Re, Mn) their acetonitrile derivatives [M2(CO)8(NCMe)2] as precursors for synthesis new di‒, tri‒ tetranuclear complexes derived from a wide range heterocyclic thiols such pyridine-2-thiol, pyrimidine-2-thiol, tetrahydropyrimidine-2-thiol, 2-mercapto-1-methylimidazole, benzimidazole-2-thiol etc. A comparative study reactivities these with various mono bidentate ligands is also subject this review. In some instances, structural aspects are discussed. The applications variety mixed-metal cluster highlighted. J. Bangladesh Acad. Sci. 47(1); 1-21: June 2023

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ژورنال

عنوان ژورنال: Journal of Bangladesh Academy of Sciences

سال: 2023

ISSN: ['0378-8121', '2224-7270']

DOI: https://doi.org/10.3329/jbas.v47i1.66442